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期刊论文 25

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钨 2

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NaOH分解 1

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Gold modified microelectrode for direct tetracycline detection

Hongtao WANG, Huimin ZHAO, Xie QUAN

《环境科学与工程前沿（英文）》 2012年 第6卷 第3期   页码 313-319 doi: 10.1007/s11783-011-0323-5

摘要： The residues of tetracycline antibiotics in water have attracted many concerns due to their harmful impact to human health. This paper reports an electrochemical sensor for the determination of tetracycline (TC) by the microelectrode, which was fabricated by electrodeposited gold colloids on tungsten tip. Cyclic voltammerty was used to study the electrochemical behavior of TC on the microelectrode. Well anodic wave was obtained at about 1.5 V in acidic solutions. Electrochemical determination of tetracycline was investigated using microelectrode by cyclic voltammetry. Under optimized conditions, the calibration curves for TC were obtained. The oxidation peak currents were linearly related to TC concentrations in the range of 1–10 mg·L and 10–100 mg·L , respectively. The detection limit was 0.09 mg·L ( / = 3).

关键词： microelectrode     tungsten tip     gold colloids     tetracycline    

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Design of ultrasonic elliptical vibration cutting system for tungsten heavy alloy

《机械工程前沿（英文）》 2022年 第17卷 第4期 doi: 10.1007/s11465-022-0715-1

摘要： Nanoscale surface roughness of tungsten heavy alloy components is required in the nuclear industry and precision instruments. In this study, a high-performance ultrasonic elliptical vibration cutting (UEVC) system is developed to solve the precision machining problem of tungsten heavy alloy. A new design method of stepped bending vibration horn based on Timoshenko’s theory is first proposed, and its design process is greatly simplified. The arrangement and working principle of piezoelectric transducers on the ultrasonic vibrator using the fifth resonant mode of bending are analyzed to realize the dual-bending vibration modes. A cutting tool is installed at the end of the ultrasonic vibration unit to output the ultrasonic elliptical vibration locus, which is verified by finite element method. The vibration unit can display different three-degree-of-freedom (3-DOF) UEVC characteristics by adjusting the corresponding position of the unit and workpiece. A dual-channel ultrasonic power supply is developed to excite the ultrasonic vibration unit, which makes the UEVC system present the resonant frequency of 41 kHz and the maximum amplitude of 14.2 μm. Different microtopography and surface roughness are obtained by the cutting experiments of tungsten heavy alloy hemispherical workpiece with the UEVC system, which validates the proposed design’s technical capability and provides optimization basis for further improving the machining quality of the curved surface components of tungsten heavy alloy.

关键词： tungsten heavy alloy     ultrasonic elliptical vibration cutting     Timoshenko’s theory     resonant mode of bending     finite element method    

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Platinum on nitrogen doped graphene and tungsten carbide supports for ammonia electro-oxidation reaction

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 930-938 doi: 10.1007/s11705-021-2130-2

摘要： Ammonia electrooxidation reaction involving multistep electron-proton transfer is a significant reaction for fuel cells, hydrogen production and understanding nitrogen cycle. Platinum has been established as the best electrocatalyst for ammonia oxidation in aqueous alkaline media. In this study, Pt/nitrogen-doped graphene (NDG) and Pt/tungsten monocarbide (WC)/NDG are synthesized by a wet chemistry method and their ammonia oxidation activities are compared to commercial Pt/C. Pt/NDG exhibits a specific activity of 0.472 mA∙cm–2, which is 44% higher than commercial Pt/C, thus establishing NDG as a more effective support than carbon black. Moreover, it is demonstrated that WC as a support also impacts the activity with further 30% increase in comparison to NDG. Surface modification with Ir resulted in the best electrocatalytic activity with Pt-Ir/WC/NDG having almost thrice the current density of commercial Pt/C. This work adds insights regarding the role of NDG and WC as efficient supports along with significant impact of Ir surface modification.

关键词： Ammonia electro-oxidation reaction     electrocatalyst supports     platinum     nitrogen doped graphene     tungsten carbide    

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Synthesis, characterization and hydrotreating performance of supported tungsten phosphide catalysts

SUN Guida, LI Cuiqing, ZHOU Zhijun, LI Fengyan

《化学科学与工程前沿（英文）》 2008年 第2卷 第2期   页码 155-164 doi: 10.1007/s11705-008-0038-8

摘要： Supported tungsten phosphide catalysts were prepared by temperature-programmed reduction of their precursors (supported phospho-tungstate catalysts) in H and characterized by X-ray diffraction (XRD), BET, temperature-programmed desorption of ammonia (NH-TPD) and X-ray photoelectron spectroscopy (XPS). The reduction-phosphiding processes of the precursors were investigated by thermogravimetry and differential thermal analysis (TG-DTA) and the suitable phosphiding temperatures were defined. The hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) activities of the catalysts were tested by using thiophene, pyridine, dibenzothiophene, carbazole and diesel oil as the feedstock. The TiO, -AlO supports and the Ni, Co promoters could remarkably increase and stabilize active W species on the catalyst surface. A suitable amount of Ni (3%–5%), Co (5%–7%) and V (1%–3%) could increase dispersivity of the W species and the BET surface area of the WP/-AlO catalyst. The WP/-AlO catalyst possesses much higher thiophene HDS and carbazole HDN activities and the WP/TiO catalyst has much higher dibenzothiophene (DBT) HDS and pyridine HDN activities. The Ni, Co and V can obviously promote the HDS activity and inhibit the HDN activity of the WP/-AlO catalyst. The G-Ni5 catalyst possesses a much higher diesel oil HDS activity than the sulphided industrial NiW/-AlO catalyst. In general, a support or promoter in the WP/-AlO catalyst which can increase the amount and dispersivity of the active W species can promote its HDS and HDN activities.

关键词： tungsten phosphide     differential thermal     catalyst surface     industrial NiW/-AlO     general    

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Thermo-elastic extended meshfree method for fracture without crack tip enrichment

A. ASADPOUR

《结构与土木工程前沿（英文）》 2015年 第9卷 第4期   页码 441-447 doi: 10.1007/s11709-015-0319-5

摘要： This is the first manuscript presenting an extended meshfree method for thermo- elastic fracture which does not exploit a crack tip enrichment. The crack is modeled by partition of unity enrichment of the displacement and temperature field. Only a step function is employed that facilitates the implementation. To ensure that crack tip is at the correct position, a Lagrange multiplier field ahead of the crack tip is introduced along a line. The Lagrange multiplier nodal parameters are discretised with the available meshfree functions. Two benchmark examples illustrate the efficiency of the method.

关键词： meshfree method     thermo-elasticity    

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Review: Tip-based vibrational spectroscopy for nanoscale analysis of emerging energy materials

Amun JARZEMBSKI, Cedric SHASKEY, Keunhan PARK

《能源前沿（英文）》 2018年 第12卷 第1期   页码 43-71 doi: 10.1007/s11708-018-0524-8

摘要： Vibrational spectroscopy is one of the key instrumentations that provide non-invasive investigation of structural and chemical composition for both organic and inorganic materials. However, diffraction of light fundamentally limits the spatial resolution of far-field vibrational spectroscopy to roughly half the wavelength. In this article, we thoroughly review the integration of atomic force microscopy (AFM) with vibrational spectroscopy to enable the nanoscale characterization of emerging energy materials, which has not been possible with far-field optical techniques. The discussed methods utilize the AFM tip as a nanoscopic tool to extract spatially resolved electronic or molecular vibrational resonance spectra of a sample illuminated by a visible or infrared (IR) light source. The absorption of light by electrons or individual functional groups within molecules leads to changes in the sample’s thermal response, optical scattering, and atomic force interactions, all of which can be readily probed by an AFM tip. For example, photothermal induced resonance (PTIR) spectroscopy methods measure a sample’s local thermal expansion or temperature rise. Therefore, they use the AFM tip as a thermal detector to directly relate absorbed IR light to the thermal response of a sample. Optical scattering methods based on scanning near-field optical microscopy (SNOM) correlate the spectrum of scattered near-field light with molecular vibrational modes. More recently, photo-induced force microscopy (PiFM) has been developed to measure the change of the optical force gradient due to the light absorption by molecular vibrational resonances using AFM’s superb sensitivity in detecting tip-sample force interactions. Such recent efforts successfully breech the diffraction limit of light to provide nanoscale spatial resolution of vibrational spectroscopy, which will become a critical technique for characterizing novel energy materials.

关键词： vibrational spectroscopy     atomic force microscopy     photo-thermal induced resonance     scanning near-field optical microscopy     tip-enhanced Raman spectroscopy     photo-induced force microscopy     molecular resonances     surface phonon polaritons     energy materials    

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Measurement and analysis of tip clearance unsteady flow spectrum in axial-flow fan rotor

LIU Bo, HOU Weimin, MA Changyou, WANG Yangang, ZHOU Qiang

《能源前沿（英文）》 2008年 第2卷 第4期   页码 448-452 doi: 10.1007/s11708-008-0088-0

摘要： The dynamic pressure measurement device and test technology are described in this study. The tip clearance unsteady flow development from the inlet to the outlet of an axial-flow rotor was revealed by analyzing pressure frequency spectrum acquired from measuring the unsteady pressure field of the tip endwall. The experiment provides test basis for thoroughly understanding the tip clearance unsteady flow and building interaction models of tip clearance flow and main flow.

关键词： development     endwall     unsteady pressure     pressure measurement     experiment    

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adsorption onto a niobium wire for electrothermal atomization atomic absorption spectrometry with a tungsten

Satoshi KANECO, Hiroaki KITANAGA, Hideyuki KATSUMATA, Tohru SUZUKI

《化学科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 432-435 doi: 10.1007/s11705-012-1219-z

摘要： In the present work, a new preconcentration method of trace elements by adsorption onto a niobium wire has been developed for electrothermal atomization atomic absorption spectrometry (ETAAS) with a tungsten tube atomizer. Detection limits (pg·mL ) by this method combined with ETAAS were 45 for bismuth, 7.0 for cadmium, 20 for copper, 1.3 for gold, 36 for lead, 65 for manganese, 9.5 for rhodium and 19 for silver.

关键词： preconcentration     adsorption onto niobium wire     electrothermal atomization atomic absorption spectrometry     tungsten tube atomizer     trace elements    

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Stress field near circular-arc interface crack tip based on electric saturation concept

Longchao DAI, Xinwei WANG

《机械工程前沿（英文）》 2009年 第4卷 第3期   页码 320-325 doi: 10.1007/s11465-009-0042-9

摘要： Within the framework of nonlinear electroelasticity, the anti-plane problem of a circular-arc interfacial crack between a circular piezoelectric inhomogeneity and an infinite piezoelectric matrix subjected to a far-field uniform loading is investigated by an electrical strip saturation model, the complex variable method, and the method of analytical continuation. Explicit closed form expressions for the complex potentials in both the matrix and the inclusion, and the stress intensity factor at the crack tip are presented. Comparison with some related solutions based on the linear electroelastic theory shows the validity of the present solutions

关键词： piezoelectric material     arc crack     strip saturation     stress intensity factor    

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钨矿物原料NaOH分解过程中抑制杂质的研究

李洪桂,李运姣,孙培梅,刘茂盛

《中国工程科学》 2000年 第2卷 第3期   页码 59-61

摘要：

从理论上较全面地研究了钨矿物原料在NaOH分解过程中直接用白钨矿及其分解产物Ca(OH)2作为抑制剂，抑制磷、砷、硅等杂质浸出的可能性及生成物的形态。进而通过实验证明在有白钨矿存在的条件下，分解所得的粗Na2WO4溶液中砷、硅的含量均比经典法低一个数量级，接近经典法净化以后的水平。

关键词： 钨冶金     NaOH分解     抑制杂质    

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Error compensation for tool-tip trace during cutting of laminated paper for rapid prototyping

Yucheng DING, Changhe LI, Dichen LI, Guoxin YU

《机械工程前沿（英文）》 2009年 第4卷 第2期   页码 111-119 doi: 10.1007/s11465-009-0020-2

摘要： Laminated object manufacturing (LOM) is one of the commercialized rapid prototyping (RP) processes, where a focused laser is usually used to cut the cross-section contours of a 3 D part and the grid hatchings of the part-exterior region on a sheet paper stack-wise. Using a laser beam as a cutter can be costly, and the thermal burning of a sheet paper along a laser scanning path can also cause an environment-polluting smoke. This paper presents a paper laminating RP system using a knife as the paper cutter instead of a laser beam. The knife holder is mounted through a radial bearing on the - positioning mechanism in such a way that the knife tip is eccentric to the bearing axis by a small distance (so-called offset). Therefore, the knife tip, which engages into the sheet paper during cutting, tends to follow the path of the -driven bearing axis by the error that depends on the path tangential and the eccentricity of the knife tip. A tractrix model is applied to describe the kinetic motion of the knife tip and a method is formulated to compensate for the tracing error of the eccentric knife tip by modifying the original cross-section contours of the part for each layer based on the tractrix equation. A study has also been performed regarding the effect of the knife tip geometry on the cutting notch of the sheet paper and on the roughness of the finished part.

关键词： rapid prototyping     laminated object manufacturing     knife-cutting     tracing error    

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Kawai型碳化钨多面砧压机的压力突破 Review

Takayuki Ishii, 刘兆东, Tomoo Katsura

《工程（英文）》 2019年 第5卷 第3期   页码 434-440 doi: 10.1016/j.eng.2019.01.013

摘要：

在众多领域中都需要扩大Kawai型碳化钨（tungsten carbide, WC）多面砧压机的压力范围，尤其是在地球科学领域。然而，40年来，在压力产生方面没有取得重大进展。

关键词： 高压     多面砧压机     碳化钨压砧     烧结的金刚石压砧     下地幔    

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钨合金的冲击拉伸行为及其本构和断裂判据的表述

张宝,丁淳彤,刘宝华,陈雪莲

《中国工程科学》 2003年 第5卷 第3期   页码 44-50

摘要：

利用飞轮式Hopkinson拉杆实验技术对钨质量分数为93% 的钨合金在-50～100℃温度范围、应变率ε=102～103s-1区间的动态拉伸性态进行了测试，提供了相应的σ-ε曲线和最大拉伸失效应变，并以此为依据建立了该合金动态拉伸行为的本构关系，提出了该合金受动载发生塑性失稳以致发生拉断的判据。利用断口分形分析理论，对试件拉伸断口微观特征所作的分析和对宏观力学性态实验所作的结论给予了有力的支持。

关键词： 动态拉伸本构模型     钨合金     断裂失效判据    

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Highly efficient and selective removal of vanadium from tungstate solutions by microbubble floating-extraction

《化学科学与工程前沿（英文）》 2023年 第17卷 第5期   页码 581-593 doi: 10.1007/s11705-022-2235-2

摘要： Selective separation of dissolved tungsten and vanadium is of great significance for the utilization of the secondary resources of these elements. In this work, selective removal of vanadium from tungstate solutions via microbubble floating-extraction was systematically investigated. The results indicated that vanadium can be more easily mineralized over tungsten from tungstate solutions using methyl trioctyl ammonium chloride as mineralization reagent under weak alkaline conditions. Owing to the higher bubble and interface mass transfer rates, high-efficiency enrichment and deep separation of vanadium could be achieved easily. Additionally, the deep recovery of tungsten and vanadium from the floated organic phase could be easily realized using a mixed solution of sodium hydroxide and sodium chloride as stripping agents. The separation mechanism mainly included the formation of hydrophobic complexes, their attachment on the surface of rising bubbles, and their mass transfer at the oil–water interface. Under the optimal conditions, the removal efficiency of vanadium reached 98.5% with tungsten loss below 8% after two-stage microbubble floating-extraction. Therefore, the microbubble floating-extraction could be an efficient approach for separating selectively vanadium from tungstate solutions, exhibiting outstanding advantages of high separation efficiency and low consumption of organic solvents.

关键词： tungsten     vanadium     selective separation     reagent mineralization     microbubble floating-extraction    

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基于高效清洁生产的全过程污染控制（WPPC）——中国钨行业典型案例研究 Article

曹宏斌, 赵赫, 张笛, 刘晨明, 林晓, 李玉平, 宁朋歌, 孙家君, 张懿, 孙峙

《工程（英文）》 2019年 第5卷 第4期   页码 768-776 doi: 10.1016/j.eng.2019.01.010

摘要：

本研究开发了一种称为全过程污染控制（WPPC）的成本效益方法，以提高过程优化的有效性。本方法以成本及环境影响最小化为目标，将废物处理作为生产过程的一部分。主要从以下方面开展了研究：①物质能量流调查，基于潜在污染物的分布和理化性质进行系统分析；②过程优化，提高不同元素的利用效率，减少污染物排放；③综合成本评估，揭示最佳优化方案。本研究选择仲钨酸铵生产作为案例，选取成本效益因子和环境影响指标进行不同优化方案的评价比较。本研究表明，考虑到潜在污染物的性质、技术创新、经济可行性、环境影响和法规要求，WPPC可有效地优化金属生产过程。

关键词： 全过程污染控制     过程优化     工业污染     钨    

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标题 作者 时间 类型 操作

Gold modified microelectrode for direct tetracycline detection

Hongtao WANG, Huimin ZHAO, Xie QUAN

期刊论文

Design of ultrasonic elliptical vibration cutting system for tungsten heavy alloy

期刊论文

Platinum on nitrogen doped graphene and tungsten carbide supports for ammonia electro-oxidation reaction

期刊论文

Synthesis, characterization and hydrotreating performance of supported tungsten phosphide catalysts

SUN Guida, LI Cuiqing, ZHOU Zhijun, LI Fengyan

期刊论文

Thermo-elastic extended meshfree method for fracture without crack tip enrichment

A. ASADPOUR

期刊论文

Review: Tip-based vibrational spectroscopy for nanoscale analysis of emerging energy materials

Amun JARZEMBSKI, Cedric SHASKEY, Keunhan PARK

期刊论文

Measurement and analysis of tip clearance unsteady flow spectrum in axial-flow fan rotor

LIU Bo, HOU Weimin, MA Changyou, WANG Yangang, ZHOU Qiang

期刊论文

adsorption onto a niobium wire for electrothermal atomization atomic absorption spectrometry with a tungsten

Satoshi KANECO, Hiroaki KITANAGA, Hideyuki KATSUMATA, Tohru SUZUKI

期刊论文

Stress field near circular-arc interface crack tip based on electric saturation concept

Longchao DAI, Xinwei WANG

期刊论文

钨矿物原料NaOH分解过程中抑制杂质的研究

李洪桂,李运姣,孙培梅,刘茂盛

期刊论文

Error compensation for tool-tip trace during cutting of laminated paper for rapid prototyping

Yucheng DING, Changhe LI, Dichen LI, Guoxin YU

期刊论文

Kawai型碳化钨多面砧压机的压力突破

Takayuki Ishii, 刘兆东, Tomoo Katsura

期刊论文

钨合金的冲击拉伸行为及其本构和断裂判据的表述

张宝,丁淳彤,刘宝华,陈雪莲

期刊论文

Highly efficient and selective removal of vanadium from tungstate solutions by microbubble floating-extraction

期刊论文

基于高效清洁生产的全过程污染控制（WPPC）——中国钨行业典型案例研究

曹宏斌, 赵赫, 张笛, 刘晨明, 林晓, 李玉平, 宁朋歌, 孙家君, 张懿, 孙峙

期刊论文